A donation drive - spearheaded by Wombwell husband and wife duo Jon Rose, 40, and Eloise, 45 - received an outpouring of support since it began last week.
Items have already been given to the refugees, who are being housed at the Holiday Inn in Manvers.
John Healey, MP for Wentworth and Dearne, said: “The council, Holiday Inn staff and the NHS are providing magnificent support and many people have contacted me offering help.”